Ethylene Methacrylic Acid

  • Abbreviation: EMAA Copolymer
  • Appearance: Transparent milky white
  • Density: 0.93-0.96g/cm³
  • CAS No.: 25053-53-6
  • HS Code: 39019090
  • Molecular Formula:(C₂H₄)ₘ·(C₄H₆O₂)ₙ

EMAA ethylene methacrylic acid copolymer is a thermoplastic resin produced through a high-pressure free-radical polymerization process by ingeniously combining ethylene (70%-95%) and methacrylic acid (5%-30%). Its unique molecular structure imparts a range of exceptional properties, making it a key player in packaging, bonding, and modification applications. The appearance is transparent milky white, and its density is usually 0.93 – 0.96g/cm³, slightly higher than that of pure polyethylene (0.91-0.93g/cm³). And EMAA resin has excellent adhesion, good flexibility and elasticity, chemical corrosion resistance, transparency and gloss.

Classification by Processing Method

  • Injection Molding Grade EMAA: Specially formulated for excellent fluidity, it quickly fills mold cavities during the injection molding process, making it suitable for manufacturing complex-shaped products such as small packaging containers and precision industrial components.
  • Extrusion Grade EMAA: Demonstrating excellent melt strength and stability, it can be used to continuously produce pipes, sheets, and films during the extrusion process. It is used in the manufacture of food packaging films, agricultural irrigation hoses, and architectural decorative panels.
  • Hot Melt Adhesive Grade EMAA: Features rapid curing and high adhesion in the heated molten state. It is specifically designed for the production of hot melt adhesives for packaging sealing, bookbinding, and woodworking applications.

Trademark

Grade

Methacrylic Acid Content (%)

Density (g/cm³)

MI (g/10min)

NUCREL™

0407HS

4.0

0.932

7.5

0910HS

8.7

0.93

10

0910

8.7

0.93

10

Main Applications of EMAA Ethylene Methacrylic Acid Copolymer

(1) Packaging Industry

Food Packaging. Used in the production of food packaging films, composite films, and packaging containers. Its excellent flexibility, chemical resistance, and low-temperature heat-sealing properties allow direct contact with food, effectively protecting it from moisture and spoilage, and extending its shelf life. For example, in potato chip bags, it can tightly wrap the chips, preventing grease from seeping out, while its heat-sealing properties ensure a secure seal.

Pharmaceutical Packaging. Commonly used in aluminum-plastic blister packaging and pharmaceutical bottle sealing. Its non-toxicity and excellent biocompatibility meet the stringent requirements of pharmaceutical packaging. Its high adhesion ensures a tight seal, protecting pharmaceuticals from moisture and oxidation, and ensuring their quality and safety.

(2) Industrial Applications

Adhesive Applications. As a hot melt adhesive and sealant, it is widely used in cable shield bonding, automotive hose manufacturing, and composite sheet production. In cable manufacturing, it firmly bonds the metal shield to the insulation layer, ensuring the cable’s electrical and mechanical properties. In the automotive industry, it is used to seal the connections of automotive hoses to prevent liquid leakage.

Modified Materials. Blending with plastics, rubber, and other materials improves the impact resistance, flexibility, and compatibility of the base material. When manufacturing agricultural irrigation hoses, adding EMAA resin enhances their flexibility and resistance to environmental stress cracking, ensuring long-term, stable use in harsh outdoor environments.

(3) Daily Goods and Consumer Goods

Daily Goods Packaging. EMAA resin is used in the packaging of toiletries, cosmetics, and household items. Its high transparency and gloss enhance the product’s appearance and appeal to consumers. Its excellent abrasion and chemical resistance ensures that the packaging is not easily damaged during daily use. For example, cosmetic bottles are both beautiful and durable.

Toys Manufacturing. Some toys are made of EMAA because of its non-toxicity and excellent flexibility, ensuring safety for children. It also resists breakage during play, extending the lifespan of the toys.

  • Excellent Adhesion. EMAA polymer exhibits extremely high adhesion to a variety of materials. When used in the packaging industry to create aluminum-plastic composite films, it tightly bonds the aluminum foil and plastic film layers, ensuring excellent barrier properties and protecting the contents from moisture and oxidation. In industrial bonding, as a hot melt adhesive or sealant, it securely bonds cable shields, automotive hoses, and composite panels, ensuring product reliability and longevity.
  • Excellent Flexibility and Elasticity. Its extremely low crystallinity gives EMAA resin excellent flexibility and elasticity, allowing films or products made from it to bend and fold easily without breaking. In food packaging, it can conform to the shape of food, providing a tight seal. When used in rubber or plastic modification additives, it can significantly improve the impact resistance and flexibility of the base material, broadening its application range.
  • Chemical Resistance. It is resistant to a variety of chemicals, including oils, fats, acids, and salts. In food packaging, it safely contacts various oily foods without being dissolved or chemically reacting with them, ensuring food safety and quality. In the industrial sector, it is used to manufacture corrosion-resistant pipes and containers, ensuring stable operation in harsh chemical environments.
  • Transparency and Gloss. The ethylene methacrylic acid copolymer exhibits excellent transparency and gloss, allowing packaging materials to clearly display contents and enhance product appeal. It is commonly used in high-end food and cosmetic packaging, enhancing product competitiveness.

1. Ethylene Segments: Laying the Foundation for Performance

As the primary component of the backbone, ethylene provides EMAA polymer with numerous fundamental advantages. Its non-polar molecular structure imparts excellent water resistance, making it impermeable to water molecules and effectively protecting it from humid environments. Furthermore, the ethylene segments impart exceptional flexibility, allowing EMAA resin to maintain excellent deformation capacity in diverse environments and resist brittle cracking. Furthermore, it exhibits strong resistance to a wide range of chemicals, from oils and fats to common acidic and alkaline solutions, ensuring the stability of the product in complex chemical environments.

2. Methacrylic Acid Groups: Imparting Key Properties

The introduction of methacrylic acid is key to the exceptional performance of EMAA resin. Its polar groups significantly enhance the resin’s adhesion to polar substrates such as metal foil (such as aluminum foil), nylon, and paper. For example, in aluminum foil lamination, EMAA forms a strong bond with the foil, resulting in high peel strength and ensuring the structural integrity of the composite product. Methacrylic acid also enhances the material’s toughness, allowing the product to effectively absorb energy and prevent cracking when subjected to external impact. Furthermore, it imparts EMAA with hot-tack strength, enabling it to quickly and tightly bond to other materials when heated. It also possesses low-temperature heat-sealing properties, enabling sealing at relatively low temperatures, reducing energy consumption and production time.

The price of EMAA resin is influenced by a variety of factors, exhibiting a certain degree of volatility. Raw material costs are a key factor influencing prices. Price fluctuations in ethylene and methacrylic acid, the primary raw materials for EMAA production, are directly transmitted to the EMAA resin market. When international crude oil prices fluctuate significantly, fluctuations in the price of crude oil, an upstream raw material for ethylene, can lead to changes in ethylene production costs, which in turn impact EMAA prices. For example, during periods of rising crude oil prices, ethylene supply costs increase, often leading to a corresponding rise in EMAA prices.

In addition, EMAA prices vary significantly across different models, specifications, and application areas. However, from an overall market perspective, EMAA prices are slightly lower than similar products such as ethylene-acrylic acid copolymer (EAA), with an average price difference of approximately $30-50 per ton. With growing market demand and cost fluctuations driven by technological advancements, the future trend of EMAA prices is uncertain. On the one hand, if raw material prices remain stable and production technology is further optimized, economies of scale and cost reductions may emerge, potentially leading to price declines. On the other hand, if demand for EMAA continues to surge in downstream emerging markets, the resulting supply imbalance could drive prices upwards.

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